Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 6, Pages 1174-1181Publisher
WILEY-BLACKWELL
DOI: 10.1002/ejic.200500973
Keywords
arene ligands; hydrides; O ligands; reactive intermediates; ruthenium
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[RuCL2(eta(6)-arene)(PR3)] complexes react with K2CO3 in the presence of water to afford the carbonatoruthenium(ii) derivatives [Ru(eta(2)-O2CO)(eta(6)-arene)(PR3)] (2; arene = p-cymene, R = Cy, Ph, or Me; arene = hexamethylbenzene, R = Me) involving a planar Ru(eta(2)-O2CO) moiety as shown by X-ray crystal structure determination of 2a (p-cymene, PCy3) and 2d (hexamethylbenzene, PMe3). The complex [Ru(eta(2)-O2CO)(p-cymene)(PCy3)] is cleanly converted in hot methanol into the dihydride [RuH2(p-cymene)(PCy3)]. The related complexes [Ru(eta(2)-O2CO)(eta(6)-arene)(IMes)] [arene = p-cymene or hexamethylbenzene, IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene] are straightforwardly prepared by treating [RuCl2(eta(6)-arene)](2) precursors with 1,3-bis(2,4,6-trimethylphenyl)imidazolium chloride and K2CO3 in THF at reflux. The removal of the carbonato ligand from complexes 2 with HBF4 in the presence of acetonitrile leads to the dicationic derivatives [Ru(eta(6)-arene)(L)(MeCN)(2)][BF4](2) (L = PR3 or IMes). ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)
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