Journal
INORGANICA CHIMICA ACTA
Volume 359, Issue 5, Pages 1390-1394Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2005.12.022
Keywords
peroxo complexes; N-containing heterocyclic ligands; niobium; crystal structure
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New water-soluble heteroleptic peroxo complexes of niobium(V) have been prepared with N-containing heterocyclic ligands. The compounds correspond to the general formula (gu)(x)[Nb(O-2)(3)(L)]center dot nH(2)O (gu = guanidinium). Three different ligands (L) have been used: picolinic acid (Hpic), picolinic acid N-oxide (HpicO) and pyrazine 2,5-dicarboxylic acid (2,5-H(2)pzdc). The Nb-V complexes have been characterized on the basis of elemental and thermal analysis as well as by IR and ESI-rnass spectrometry. The crystal structure of the peroxo complex with the picolinato N-oxide ligand, (gu)(2)[Nb(O-2)(3)(picO)] (II) has been determined, showing an eightfold-coordinated Nb atom surrounded by three peroxide groups and a picO ligand bound in a bidentate mode via the carboxylato and the N-oxide groups. The coordination polyhedron around the metal is a triangular dodecahedron. (c) 2005 Elsevier B.V. All rights reserved.
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