Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 27, Issue 6, Pages 393-398Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200500798
Keywords
atom transfer radical polymerization (ATRP); controlled radical polymerization; grafting from; MSU mesoporous silica; surface-initiated polymerization
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Mesoporous silica was used as Substrate for the grafting of alkyl halides initiators. The control over the surface-initiated polymerization of styrene and MMA, in terms of molar mass and molar mass distribution, was successfully achieved using an ATRP mechanism. The occurrence of the polymerization inside the mesopores was confirmed by thermogravimetric analysis.
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