4.4 Article

Photochemical generation and trapping of radicals from bisphenyl carbodiazone

Journal

TETRAHEDRON LETTERS
Volume 47, Issue 13, Pages 2115-2118

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2006.01.128

Keywords

bisphenyl carbodiazone; phenyl radicals; (phenyldiazenyl)carbonyl radicals; carbooxygenation

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UV irradiation at 350 nm of bisphenyl carbodiazone creates nitrogen, phenyl and (phenyldiazenyl)carbonyl radicals under mild conditions. The radicals formed were trapped by olefins and tetramethylpiperidinoxyl radicals. (c) 2006 Elsevier Ltd. All rights reserved.

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