Journal
ORGANIC LETTERS
Volume 8, Issue 7, Pages 1263-1266Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0529391
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Various organocatalysts have been designed based on molecular recognition to catalyze the asymmetric direct aldol reaction of ketones with aryl and alkyl alpha-keto acids, affording beta-hydroxyl carboxylic acids with a tertiary stereogenic center with excellent enantioselectivities of up to 98% ee. A linear effect was observed for the reaction, demonstrating a single molecule of the catalyst involved in the catalysis.
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