Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 110, Issue 12, Pages 6072-6080Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp0531208
Keywords
-
Categories
Ask authors/readers for more resources
The proton conductivity of radiation-grafted ethylenetetrafluoroethylene-grafted-poly(styrene sulfonic) acid (ETFE-g-PSSA) and Nafion 117 membranes between 25 and -37 degrees C is reported. The freezing of water in the membranes, which strongly depends on the internal acid concentration, results in a 4-fold decrease in proton conductivity. The activation energies before and after the freezing of the membranes are similar to 0.15 and 0.4 eV, consistent with proton transport through liquid water and strongly bound water, respectively. Differential scanning calorimetry data show that up to 14 H2O molecules per H+/SO3- group remain unfrozen at subzero temperatures and are believed to be responsible for the low temperature conductivity that is observed. These results indicate that proton conductivity in membranes may be achieved via strongly bound and highly polarized water.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available