Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 71, Issue 7, Pages 2881-2884Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo052542a
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New 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) derivatives (1 and 2) were synthesized as an off-on fluorescent chemosensor and fluorescent chemodosimeter for Cu2+ and Pb2+. Compound 1 displayed selective and large chelation enhanced fluorescence effects with Pb2+ and Cu2+ among the metal ions examined. On the other hand, compound 2, a fluorescent chemodosimeter, effectively recognized Cu2+ via a selective hydrolysis of the acetyl group.
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