Oxygen reduction reaction on electrodeposited zinc oxide electrodes in KC1 solution at 70°C

The reduction of oxygen was studied in 0.1 M KCl at 70 degrees C using the rotating disk electrode (RDE) technique on platinum and electrodeposited ZnO thin film electrodes deposited on platinum substrates. In the absence of Zn2+, ions in solution, a Tafel slope of 139 mV dec(-1) was obtained, a value close to that measured on bare platinum electrode (133 mV dec(-1)) and ascribed to the limitation of the reaction rate by the first electron transfer. The main difference between the noble metal and the oxide electrode was a shift of the curves towards more negative potentials. In the presence of Zn2+ ions, the current density decreased significantly and the Tafel slope was measured at 282 mV dec(-1) showing that the electrode was partially blocked by zinc oxide formation reaction intermediates. (c) 2005 Elsevier Ltd. All rights reserved.