Journal
TRENDS IN BIOTECHNOLOGY
Volume 24, Issue 4, Pages 163-171Publisher
ELSEVIER SCIENCE LONDON
DOI: 10.1016/j.tibtech.2006.02.003
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Biocatalytic oxygenation chemistry is a rapidly evolving field in which monooxygenases are the tools of choice. Monooxygenases catalyze many industrially important synthetic transformations; however, their use in preparative applications is hampered by their intrinsic requirement for reducing equivalents. As a result, nonenzymatic strategies - where the reducing equivalents are introduced directly into the catalytic cycle - are being developed to supersede the well-established enzymatic NAD(P)H regeneration systems currently in use. In this review we summarize and evaluate recent achievements in this area.
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