4.5 Article

Palladium-catalyzed cross-coupling reactions of dry arenediazonium o-benzenedisulfonimides with aryltin compounds

Journal

SYNTHESIS-STUTTGART
Volume -, Issue 7, Pages 1117-1122

Publisher

GEORG THIEME VERLAG KG
DOI: 10.1055/s-2006-926373

Keywords

palladium; Stille reaction; cross-coupling; diazonium compounds; sulfur

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dThe palladium-catalyzed cross-coupling reaction between various arenediazonium o-benzenedisulfonimides and aryltin derivatives is described. The procedure is general, easy and gives pure biaryls in good yields (25 examples, average yield 79%). o-Benzenedisulfonimide can be recovered (> 80%) and reused to prepare again the starting material.

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