Journal
SYNTHESIS-STUTTGART
Volume -, Issue 7, Pages 1127-1132Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2006-926378
Keywords
imines; enaminones; erbium triflate; Lewis acids; catalysis
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Aldimines, ketimines, and enaminones can be obtained under erbium(III) triflate catalysis. The reaction mechanism is that typical of imine synthesis. The role of the catalyst is demonstrated for the synthesis of aromatic imines. In contrast to CeCl3/NaI addition to unsaturated aldehydes, which results in Michael addition, no Michael adduct was observed under erbium(III) triflate catalysis.
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