Journal
ORGANOMETALLICS
Volume 25, Issue 8, Pages 1836-1850Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om058042p
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This review describes the synthesis. reaction chemistry, structures, and bonding of early-late heterodi-, heterotri-, and heterotetrametallic transition-metal complexes by applying the molecular Tinkertoy approach. As connecting units between the different metal atoms, pi-conjugated carbon-rich organic and/or inorganic Groups can be used. The electrochemical behavior of such one-dimensional molecular wire molecules, coordination polymers, starlike structures, and dendritic oriented transition-metal species, respectively, is presented as well.
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