4.5 Article

Tuning of copper nanocrystals optical properties with their shapes

Journal

JOURNAL OF PHYSICAL CHEMISTRY B
Volume 110, Issue 14, Pages 7208-7212

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jp0601567

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Copper nanocrystals are obtained by chemical reduction of copper ions in mixed reverse micelles. A large excess of reducing agent favors producing a new generation of shaped copper nanocrystals as nanodisks, elongated nanocrystals, and cubes. By using UV-Visible spectroscopy and numerical optical simulations we demonstrate that the optical properties are tuned by the relative proportions of spheres and nanodisks.

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