Journal
ORGANIC LETTERS
Volume 8, Issue 8, Pages 1637-1640Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0602452
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Ultrafast time-resolved studies of the photochemistry of 2-azidonitrobenzene demonstrate that the lifetimes of excited singlet 2-azidonitrobenzene and 2-nitrophenylnitrene are 500 fs and 8.3 ps, respectively, in solution at ambient temperature. The singlet nitrene is a discrete intermediate but is too short lived to undergo bimolecular reactions.
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