4.8 Article

Facile synthesis of enantiopure chiral molecular rectangles exhibiting induced circular dichroism

Journal

ORGANIC LETTERS
Volume 8, Issue 8, Pages 1701-1704

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol060365+

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Funding

  1. NIGMS NIH HHS [GM-57052] Funding Source: Medline

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The facile syntheses of enantiopure molecular rectangles using 1,8-bis(trans-Pt(PEt3)(2)(NO3))anthracene and optically pure D- or L-tartrate are reported in high yields. These self-assembled macrocycles are unique examples where the phenomenon of induced chiral dichroism (ICD) has been observed in chiral metallosupramolecular assemblies.

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