Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 12, Issue 13, Pages 3636-3646Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200501473
Keywords
arylation; copper; cross-coupling; homogeneous catalysis; N,O ligands
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A new and readily available bidentate ligand, namely, pyrrolidine-2-phosphonic acid phenyl monoester (PPAPM), has been developed for the coppercatalyzed formation of C-N, C-O, and P-C bonds, and various N-, O-, and P-arylation products were synthesized in good to excellent yields by using the Cul/ PPAPM catalyst system. Addition of the PPAPM ligand greatly increases the reactivity of the copper catalyst, and the resulting versatile and efficient catalyst system is of widespread and practical application in cross-coupling reactions.
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