Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 71, Issue 8, Pages 3264-3266Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo060038f
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Syntheses of annelated and functionalized ss-trithiophenes (dithieno[2,3-b:3 ',2 '-d]thiophenes), building blocks for the helically annelated, cross-conjugated ss-oligothiophenes, are reported. UV-vis spectra reveal that the effect of octyl substituents on the onset of electronic absorption in annelated ss-trithiophenes is negligible compared to the effect of helical distortion in the higher ss-oligothiophenes.
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