4.7 Article Proceedings Paper

Recent developments in evaporated CdTe solar cells

Journal

SOLAR ENERGY MATERIALS AND SOLAR CELLS
Volume 90, Issue 6, Pages 664-677

Publisher

ELSEVIER
DOI: 10.1016/j.solmat.2005.04.003

Keywords

solar cells; thin films; CdTe; flexible solar cells; space photovoltaics

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Recent developments in the technology of high vacuum evaporated CdTe solar cells are reviewed. High-efficiency solar cells of efficiencies up to 12.5% have been developed on sodalime glass substrates with a low-temperature (< 450 degrees C) process. This simple process is suitable for in-line production of large-area solar modules on glass as well as on flexible polymer films with a roll-to-roll deposition process. Flexible and lightweight CdTe solar cells with a record efficiency of 11.4% have been developed in a superstrate configuration, and 3.5% efficiency mini-modules have been realised in a preliminary development. Deposition of high-temperature stable ITO front contact layer on polyimide is important for high-efficiency cells, as the layer should withstand processing steps maintaining its high electrical conductivity and optical transparency. Another development is an application of a transparent conducting oxide (TCO) ITO as a back electrical contact on CdTe leading to first bifacial CdTe solar cells, which can be illuminated from either or both sides. Accelerated long-term stability tests show that light soaking improves the efficiency of CdTe solar cells with ITO back contacts and performance does not degrade. Stability of CdTe solar cells has been measured after irradiation with high-energy protons and electrons of different fluences. These solar cells exhibit superior radiation tolerance compared to conventional Si and GaAs solar cells for space applications. Because of extreme stability, and high specific power (kW/kg) of flexible solar cells, CdTe has a promising potential for space applications. (c) 2005 Elsevier B.V. All rights reserved.

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