Journal
JOURNAL OF MOLECULAR STRUCTURE
Volume 787, Issue 1-3, Pages 163-166Publisher
ELSEVIER
DOI: 10.1016/j.molstruc.2005.10.043
Keywords
photoelectron spectra; structure characterization; Rydberg levels; azulene; naphthalene
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The applicability of Rydberg spectroscopy as a method to fingerprint molecular structures is demonstrated on the example of the azulene/naphthalene system. The fingerprint characteristics of Rydberg spectra are distinctly different from those of other techniques, making the technique useful for the characterization of large-scale structural features. In addition, universal applicability to all neutral or positively charged ions, from small molecules to large composite or polymeric systems, is coupled with straightforward combination with traditional mass spectrometry. (c) 2005 Published by Elsevier B.V.
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