Journal
INORGANIC CHEMISTRY
Volume 45, Issue 8, Pages 3155-3157Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic060089v
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A highly efficient and general method based on transmetalation with an organozinc reagent is developed for selective preparation of homo- and heteroleptic meridional tris-cyclometalated iridium complexes. The molecular structure of mer-Ir(1-piq)(2)(PPY) (2) has been determined by a single-crystal X-ray diffraction analysis. The emission properties of a series of meridional complexes are reported.
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