Journal
INORGANIC CHEMISTRY
Volume 45, Issue 8, Pages 3158-3160Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic060080t
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Clusters containing nine lanthanide and six sodium ions are crystallized with the help of a tridentate ligand bearing a phosphonic acid group; the structure of the Eu-III compound reveals a host-guest assembly Eu subset of Na6Eu8L16 with a substantial quantum yield (32%). A similar Eu-III-Yb-III structure displays dual luminescence in the visible (Eu-III) and NIR (Yb-III) ranges.
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