Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 110, Issue 15, Pages 7617-7620Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp060702w
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The codoping effect mechanism of Al and P on the solubility enhancement of Er3+ ion in SiO2 glass was clarified by electron spin-echo envelope modulation spectroscopy. It turned out that doped P ions preferentially coordinate to the Er3+ ion to form a solvation shell structure, and the environment is similar to that in phosphate glass, while doped Al ions do not form such a selective solvation structure, taking octahedral coordination. This striking difference indicates that the primary roles of the P-doping and the M-doping are attributed to enthalpy of mixing and to entropy of mixing, respectively.
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