Journal
TETRAHEDRON
Volume 62, Issue 17, Pages 3989-3996Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2006.02.027
Keywords
electrolysis; stereoselectivity; electrocatalytic transformation; mediators; malonate; alkylidenecyanoacetates; substituted cyclopropanes
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Electrolysis of malonate and alkylidenecyanoacetates in alcohols in an undivided cell in the presence of NaBr results in stereoselective formation of (E)-3-substituted 2-cyanocyclopropane-1,1,2-tricarboxylates in 75-90% yields. (c) 2006 Published by Elsevier Ltd.
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