Journal
ORGANIC LETTERS
Volume 8, Issue 9, Pages 1957-1959Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0606839
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A study concerning the gold(l)-catalyzed rearrangement of butynediol monobenzoates into functionalized 2,5-dihydrofurans is described. The mild reaction conditions employed allow the efficient and rapid stereoselective synthesis of a variety of 2,5-dihydrofurans via a sequence of two gold(l)-catalyzed isomerization steps.
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