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JOURNAL OF APPLIED PHYSICS
Volume 99, Issue 9, Pages -Publisher
AIP Publishing
DOI: 10.1063/1.2195890
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The mechanism of charge separation in polymeric bulk heterojunction photovoltaic cells is usually described as electron transfer from the absorbing polymer to an electron acceptor material such as (6,6)-phenyl C-61 butyric acid methyl ester (PCBM). We consider the possibility of energy transfer to PCBM as another potential mechanism for charge separation. We demonstrate resonance energy transfer from a red-emitting organic chromophore (Nile red) to PCBM and measure a Forster radius of 3.1 nm. Using standard Forster energy transfer theory, we calculate a Forster radius (R-0) of around 2.7 nm for this donor-acceptor pair in polystyrene. Nile red has a similar emission spectrum to commonly used conjugated polymers used in polymer/PCBM photovoltaic cells. We consider the implications of an energy transfer mechanism on the design requirements for future photovoltaic cells. (C) 2006 American Institute of Physics.
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