4.5 Review

Gas-phase ion chemistry in organometallic systems

Journal

MASS SPECTROMETRY REVIEWS
Volume 25, Issue 3, Pages 483-513

Publisher

WILEY-BLACKWELL
DOI: 10.1002/mas.20075

Keywords

gas-phase ion chemistry; organometallic systems; reaction mechanisms; mass spectrometry

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This review essentially deals with positive ion/molecule reactions occurring in gas-phase organometallic systems, adn encompasses a period of time of approximately 7 years, going from 1997 to early 2004. Following the example of the excellent review by Eller & Schwarz (1991; Chem Rev 91:1121-1177), in the first part, results of reaction of naked ions are presented by grouping them according to the neutral substrate, while in the second part, ligated ions are grouped according to the different ligands. Whenever possible, comparison among similar studies is attemted, and general trends of reactivities are evidenced. (c) 2005 Wiley Periodicals, Inc.

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