Journal
RUSSIAN CHEMICAL BULLETIN
Volume 55, Issue 5, Pages 821-827Publisher
SPRINGER
DOI: 10.1007/s11172-006-0338-4
Keywords
enantioselective phase transfer catalysis; chiral cobalt(III) complexes; cyanohydrins; aldehydes; trimethylsilyl cyanide; amino acids; salens
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Chiral coordinatively saturated cobalt(III) complexes with Schiff bases of enantiopure amino acids are formed as Lambda- and Delta-isomers, which are not transformed into each other under normal conditions. These complexes catalyze the formation of enantiomerically enriched cyanohydrins from aldehydes and Me3SiCN under homo- and heterogeneous catalysis.
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