Journal
COORDINATION CHEMISTRY REVIEWS
Volume 250, Issue 9-10, Pages 1122-1140Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2005.11.020
Keywords
pentalene; sandwich compounds; organometallic; molecular wires; transition metals; f-elements
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Carbocyclic, aromatic ligands have always played a central role in the growth of organometallic chemistry. In this review, we present work from our own laboratories and those of others on the development of the coordination chemistry of the eight-membered, bicyclic pentalene ring system, and its application to the synthesis of new types of organometallic compounds throughout the periodic table. (c) 2005 Elsevier B.V. All rights reserved.
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