Journal
SYNTHESIS-STUTTGART
Volume -, Issue 9, Pages 1443-1446Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2006-926423
Keywords
triphenylphosphine; dimethyl acetylenedicarboxylate; zwitterions; electron-deficient styrenes; phosphoranes
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The zwitterion formed from triphenylphosphine and DMAD adds to electron-deficient styrenes to form stable cyclopentenyl phosphoranes. This is the first example of such a zwitterion in which the phosphine is incorporated into the product.
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