Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 110, Issue 17, Pages 8540-8543Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp061083u
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New Pt-in-CeO2 catalyst prepared by microemulsion method is shown to give higher activity for a water-gas shift reaction but with no formation of CH4, the side product from hydrogenation of carbon oxides using a hydrogen-rich reformate as compared to conventional Pt-on-CeO2 catalysts. Detailed characterization by DRIFT analysis and temperature programmed reduction presented in this work clearly suggest the ceria coverage on Pt inhibits the metal from forming a strong CO adsorption.
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