4.5 Article

Comparison of linear and 2D IR spectra in the presence of fast exchange

Journal

JOURNAL OF PHYSICAL CHEMISTRY B
Volume 110, Issue 17, Pages 8531-8534

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jp060935n

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Funding

  1. NCRR NIH HHS [P41 RR001348, P41 RR001348-26, P41-RR01348] Funding Source: Medline

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The few picosecond time scale H-bond making and breaking in the system acetonitrile-methanol dominates the mechanism of vibrational coherence transfer that is evident in the shapes of both the linear and nonlinear IR spectra of the CN group.

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