Journal
CHEMISTRY LETTERS
Volume 35, Issue 5, Pages 492-493Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2006.492
Keywords
-
Categories
Ask authors/readers for more resources
D-L conversion pathways of alpha-alanine have been discovered by theoretical search of potential energy surfaces at the level of B3LYP/6-311++G(d,p). No direct conversion channel via only one transition state could be found between D and L optical isomers of alanine. It is demonstrated that there are four types of conversion channels in chiral amino acids. The interconversion of four functional groups (H, CH3, NH2, and COOH) around the asymmetric carbon atom can occur as rotation of a single-bonded pair of two groups involving either NH2 or COOH together with H or CH3.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available