4.4 Article

The Newman-Kwart rearrangement re-evaluated by microwave synthesis

Journal

TETRAHEDRON
Volume 62, Issue 19, Pages 4685-4689

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2005.12.063

Keywords

microwave; Newman-Kwart; rearrangement

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The Newman-Kwart rearrangement (NKR) has been re-evaluated by microwave heating. Microwave technology has proven to be ideal for investigating this high temperature rearrangement and facilitated the confirmation of many aspects of this valuable reaction. Comparisons between thermal and microwave results indicate no evidence of a significant microwave effect. (c) 2006 Published by Elsevier Ltd.

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