Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 110, Issue 18, Pages 9022-9026Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp056922b
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The nanostructure origins of three distinct and strong fluorescence bands of C-60 in room-temperature pyridine are reported for the first time. Fluorescence study and in-situ TEM observation on C-60-pyridine solutions with different setting times exhibit that the blue fluorescence peaks centered at 440 nm originate from C-60 nanoparticles; the yellow-green fluorescence band located at 575 nm derives from C-60 lace-like cluster; and the salmon pink fluorescence band around 700 nm arises from C-60 microbulk in solution. The conclusions are supported further by investigation on the C-60-toluene system as well.
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