Journal
ORGANIC LETTERS
Volume 8, Issue 10, Pages 2063-2066Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0604724
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The Cu(I)-catalyzed cycloaddition of alkynes and azides (click reaction) provides a robust method for the construction of macrocyclic small molecules via an intramolecular macrocycloaddition. A three-subunit system has been used to explore the tolerance of this macrocycloaddition to variations of stereochemistries and substituents.
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