Journal
ORGANIC LETTERS
Volume 8, Issue 10, Pages 2071-2073Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0604771
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- NIGMS NIH HHS [GM-33328-21] Funding Source: Medline
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An enantio- and diastereoselective Sakurai-Hosomi reaction, catalyzed by chiral scandium pyridyl-bis(oxazoline) (pybox) complexes, has been developed. Both alkyl- and aryl-substituted allylsilanes are effective coupling partners with N-phenylglyoxamide. Applications of this reaction to the asymmetric syntheses of N-BOC D-alloisoleucine and D-isoleucine are described.
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