Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 12, Issue 15, Pages 3975-3983Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200600114
Keywords
carbon nanotubes; cyclic voltammetry; fullerenes; noncovalent interactions; supramolecular chemistry
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Noncovalent interactions between purified HiPCO single-wall carbon nanotubes (SWNT) and a [60]fullerene-pyrene dyad, synthesized through a regioselective double-cyclopropanation process, produce stable suspensions in which the tubes are very well dispersed, as evidenced by microscopy characterization. Cyclic voltammetry experiments and photophysical characterization of the suspensions in organic solvents are all indicative of sizeable interactions of the pyrene moiety with the SWNT and, therefore, of the prevalence in solution of [60]fullerene-pyrene-SWNT hybrids.
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