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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 128, Issue 19, Pages 6480-6485Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja061035n
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The unexpected isomerization of N-ethyl [6,6]-pyrrolidino-Y3N@C-80 to the [5,6] regioisomer is reported, as well as the synthesis, characterization, and electrochemical analysis of Er3N@C-80 derivatives. A complete electrochemical study of the M3N@C-80 species (M = Sc, Y, Er) and their derivatives is presented. We introduce electrochemistry as a new tool in the characterization of the [5,6] and [6,6] regioisomers of trimetallic nitride endohedral metallofullerenes.
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