Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 110, Issue 19, Pages 9383-9386Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp060904s
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Orthorhombic V2O5 single-crystalline nanobelts with widths of 100-300 nm, thicknesses of 30-40 nm, and lengths up to tens of micrometers have been synthesized on a large scale in a hydrogen peroxide aqueous solution by an environmentally friendly chemical route. Such nanobelts grow along the direction of [ 010]. The influence of the reaction time on the crystal structures and morphologies of the resulting products are investigated. A probable dehydration-recrystallization-cleavage mechanism for the formation of V2O5 nanobelts is proposed. The experiments demonstrate that the use of a nanosized belt-like structure can considerably enhance the specific discharge capacity in lithium-ion batteries.
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