4.8 Article

Quantum-tunneling-induced Kondo effect in single molecular magnets

Journal

PHYSICAL REVIEW LETTERS
Volume 96, Issue 19, Pages -

Publisher

AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.96.196601

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We consider transport through a single-molecule magnet strongly coupled to metallic electrodes. We demonstrate that, for a half-integer spin of the molecule, electron and spin tunneling cooperate to produce both quantum tunneling of the magnetic moment and a Kondo effect in the linear conductance. The Kondo temperature depends sensitively on the ratio of the transverse and easy-axis anisotropies in a nonmonotonic way. The magnetic symmetry of the transverse anisotropy imposes a selection rule on the total spin for the occurrence of the Kondo effect which deviates from the usual even-odd alternation.

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