Journal
ELECTROCHIMICA ACTA
Volume 51, Issue 19, Pages 4089-4095Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2005.11.027
Keywords
spinel LiMn2O4; nanocrystalline; positive electrode; 3 V; cyclability; lithium-ion battery
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Spherical lithium manganese oxide spinet was synthesized by an ultrasonic spray pyrolysis method, and has been characterized using X-ray diffraction, scanning electron microscopy, transimission electron microscopy and electrochemical cycling at 3 V regions. The LiMn2O4 powders were composed of about 10 nm-sized primary particles. The delivered discharge capacity of the synthesized nano-material was 125 mAh g(-1) between 2.4 and 3.5 V and its retention was about 96% upon 50 cycling. From the high resolution transmission electron microscopic study, it was found that structural transition of the parent material did not occur even after the 50th electrochemical cycling on the 3 V region. It seems that the reversible structural change is possible for nanocrystalline LiMn2O4 as observed by the X-ray diffraction and transition electron microscopic observations. (c) 2005 Elsevier Ltd. All rights reserved.
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