Journal
ORGANOMETALLICS
Volume 25, Issue 11, Pages 2715-2718Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om060138b
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Novel chiral and enantiomerically pure phospholes, which have axially chiral biaryl substituents at the 2- and 5-positions of the phosphole rings, have been prepared and converted into a Variety of phosphametallocenes with retention of the chiral substituents. The phospholes and the phosphametallocenes have been applied to palladium-catalyzed asymmetric hydrosilylation of 5,5-dimethyl-1-hexen-3-yne to give an axially chiral allenylsilane with high enantioselectivity of up to 92% ee.
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