Journal
ORGANIC LETTERS
Volume 8, Issue 11, Pages 2257-2260Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol060327q
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- NIGMS NIH HHS [R01 GM67173] Funding Source: Medline
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Palladium(II) complexes bearing a single N-heterocyclic carbene ligand serve as effective catalysts for the aerobic oxidative cyclization of alkenes with pendant sulfonamides. The use of carboxylic acid cocatalysts (AcOH and PhCO2H) often leads to significant improvements in catalyst stability and product yield and enables catalytic turnover to be achieved with air, rather than pure oxygen gas, as the source of O-2.
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