Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 20, Pages 2170-2172Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b603419e
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The reaction of protected 4,5-diiodoimidazoles with (PhMe2CCH2)(2)CuLi regioselectively provides 5-cuprated imidazoles, which readily react with various electrophiles furnishing functionalized imidazoles in good yields; remarkably, these resulting mono-iodoimidazoles undergo again an iodine-copper exchange reaction in the presence of sensitive functional groups, like an aldehyde or a ketone.
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