Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 20, Pages 2164-2166Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b602116f
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Analysis of model compounds such as Fe-2(CO)(6), C-2 and HBBH shows that pi-bonds left to themselves are shorter than sigma-bonds; in many ways sigma-bonds prevent pi-bonds from adopting their optimal shorter distances.
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