Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 348, Issue 9, Pages 1029-1032Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200606149
Keywords
enantioselectivity; hydrosilylation; imine; ligands; zinc
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The highly enantioselective reduction of imines is achieved by employing chiral Zn/diamine catalysts. This new catalytic protocol offers attractive features such as use of a non-precious metal and an inexpensive silane, easy modification of chiral diamine ligands and provides ready access to chiral amines in good yields and with excellent enantioselectivities.
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