Journal
CHEMICAL & PHARMACEUTICAL BULLETIN
Volume 54, Issue 6, Pages 788-794Publisher
PHARMACEUTICAL SOC JAPAN
DOI: 10.1248/cpb.54.788
Keywords
7-substituted indole; thallation; formyl group; tripeptide
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7-Substituted (Cl, Br, I) indoles were synthesized by using thallation of N-formylindoline as a key reaction. Two precursor tripeptides for the right-hand segment of chloropeptin were synthesized by using (R)-7'-iodo and 7'-bromotryptophans derived from each 7-substituted indole (I, Br) obtained by the above procedure.
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