4.5 Article

A new precursor for organo-osmium complexes

Journal

INORGANICA CHIMICA ACTA
Volume 359, Issue 9, Pages 2644-2649

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2005.09.070

Keywords

cyclopentadienyl; osmium; phosphine; X-ray structures

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The use of potassium osmate, K-2[OsO2(OH)(4)], as a precursor for some cyclopentadienyl-osmium complexes is described. The X-ray structures of OsBr(PPh3)(2)CP, OsCl(dppe)Cp and OsX(dppe)Cp* (X = Cl, Br) are reported. (c) 2006 Elsevier B.V. All rights reserved.

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