Journal
JOURNAL OF CHEMICAL THERMODYNAMICS
Volume 38, Issue 6, Pages 717-723Publisher
ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jct.2005.08.003
Keywords
aliphatic acetates; transpiration method; vapour pressure; enthalpy of vaporization; Kovat's index
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Vapour pressures and the molar enthalpies of vaporization Delta H-g(l)m of the linear aliphatic acetates C-8-C-16 have been determined by the transpiration method. Kovat's indices of these compounds were measured by capillary gas-chromatography. A linear correlation of enthalpies of vaporization Delta H-g(l)m at T = 298.15 K of the acetates studied with the Kovat's indices as well as with the number of carbon atoms has been found. (C) 2005 Elsevier Ltd. All rights reserved.
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