Journal
APPLIED CATALYSIS B-ENVIRONMENTAL
Volume 65, Issue 3-4, Pages 261-268Publisher
ELSEVIER
DOI: 10.1016/j.apcatb.2006.02.008
Keywords
CWPO; hydrogen peroxide; phenol oxidation; active carbon iron supported catalyst; Fe/AC
Ask authors/readers for more resources
A Fe on activated carbon catalyst has been prepared and tested for phenol oxidation with H2O2 in aqueous solution at low concentration (100 mg/L). Working at 50 degrees C, initial pH 3 and a dose of H2O2 corresponding to the stoichiometric amount (500 mg/L) complete removal of phenol and a high TOC reduction (around 85%) has been reached. Oxidation of phenol gives rise to highly toxic aromatic intermediates which finally disappear completely evolving to short-chain organic acids. Some of these last showed to be fairly resistant to oxidation being responsible for the residual TOC. In long-term continuous experiments the catalyst undergoes a significant loss of activity in a relatively short term (20-25 h) due to Fe leaching, this being related with the amount of oxalic acid produced. Deactivation may also be caused by active sites blockage due to polymeric deposits on whose formation some evidences were found. Washing with IN NaOH solution allows to recover the activity although complete restoration was not achieved. (c) 2006 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available